Synthesis, Characterization and Investigation of Photocatalytic Activity of transition metal-doped TiO2 Nanostructures

Authors

  • M. Hosseini-Zori Department of Inorganic Pigments and Glazes, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran.
  • Z. Mokhtari shourijeh Department of Environmental Research, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran.
Abstract:

In this work, M-doped TiO2 nanostructures (M: Fe, Co and Ni) were synthesized by reverse microemulsion method. The as-prepared products were analyzed by different techniques such as scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR). The effect of various dopants (Fe, Co and Ni) on band gap and photocatalytic properties of TiO2 was investigated. The decolorization abilities of the as-prepared M-TiO2 nanostructures (M = Fe, Co and Ni) under UV and visible irradiation were investigated using three dyes: Acid Red 1, Reactive Blue 21 and Indigo Carmine. The role of  pH value and reaction time on photocatalytic performance of products was also studied. The results showed that the degradation of dyes in lower pH is more and photocatalytic performance Fe-doped TiO2 is better than the others. Kinetic investigation of the photodegradation illustrated reactions were following the Langmuir-Hinshelwood mechanism.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Synthesis and Characterization of Doped TiO2 Nanoparticles by the Sol-Gel Method and Investigation of Photocatalytic Activity

Cu2+,Ce3+-doped nanostructure TiO2 -coated Nd3+ (TiO2 /Nd3+) were prepared by sol-gel method. TiO2 were synthesized by the sol-gel method using tetra n-butyl orthotitanat (TBT) as a precursor. The prepared nanoparticles characterized by FT-IR, XRD, SEM- EDS and TEM. The XRD showed that the major phase of nanocomposite is anatase. The morphology of the TiO2/Nd3+/Cu2+and TiO2 /Nd3+/Ce3+ microsphe...

full text

Investigation of Photocatalytic Activity of Nd-Doped ZnO Nanoparticles Using Brilliant Green Dye: Synthesis and Characterization

An Nd doped ZnO (1-5%) photocatalyst was successfully synthesized via chemical co-precipitation method. The optical property, nature, and morphology of the synthesized nanoparticles were analyzed by UV-Visible, XRD, and FESEM respectively. XRD study reveals that Nd has been effectively incorporated in the ZnO lattice in the lower level dosage; however, the crystalline nature has been distor...

full text

Sonochemical synthesis of undoped and Co-doped ZnO nanostructures and investigation of optical and photocatalytic properties

In this paper, undopedZnO and Co-ZnOnano structureswith different molar ratio of Cobalt have been synthesized by the sonochemical method. Structure have been characterized by Fourier Transform (FTIR) and UV–Vis spectroscopy,Scanning Electron Microscopy (SEM), Energy Dispersive Analytical X-Ray (EDAX), and X-Ray Diffraction (XRD) methods. Moreover, the direct band gap has been calculated by Tauc...

full text

Sonochemical synthesis of undoped and Co-doped ZnO nanostructures and investigation of optical and photocatalytic properties

In this paper, undopedZnO and Co-ZnOnano structureswith different molar ratio of Cobalt have been synthesized by the sonochemical method. Structure have been characterized by Fourier Transform (FTIR) and UV–Vis spectroscopy,Scanning Electron Microscopy (SEM), Energy Dispersive Analytical X-Ray (EDAX), and X-Ray Diffraction (XRD) methods. Moreover, the direct band gap has been calculated by Tauc...

full text

synthesis and characterization of some macrocyclic schiff bases

ماکروسیکلهای شیف باز از اهمیت زیادی در شیمی آلی و دارویی برخوردار می باشند. این ماکروسیکلها با دارابودن گروه های مناسب در مکانهای مناسب می توانند فلزاتی مثل مس، نیکل و ... را در حفره های خود به دام انداخته، کمپلکسهای پایدار تولید نمایند. در این پایان نامه ابتدا یک دی آلدئید آروماتیک از گلیسیرین تهیه می شود و در مرحله بعدی واکنش با دی آمینهای آروماتیک و یا آلیفاتیک در رقتهای بسیار زیاد منجر به ت...

15 صفحه اول

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 11  issue 4

pages  209- 220

publication date 2018-11-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023